Just a word of caution if you plan to go see Mount Aso. Sometimes the area up to 1 km from crater is closed to the public due to higher poisonous gas emissions. Lately it has been closed for months. Always check first to see if the area is open, and if not, have a back up plan.
Kyushu has a lot to see that's off the beaten path. Start at Fukuoka. Don't miss the Nanzoin Temple which is one of Japan's finest yet almost totally unknown to the outside world and completely free
Look into a Fukuoka Tourist City Pass also.
You can also see a lot of previews on the best there is to see here.
Kagoshima could fill up a whole day nicely too - Sakurajima is wonderful, plus the Senganen Garden is superb.
Beppu is famous for its hot springs, but its Hells Tour, plus monkey park/aquarium are all terrific. Nagasaki is the most interesting city on the island and worth a couple of days.